that helped you sort through some of the explanations about that male guppy. [Of course there's alway the possibility that hormones are just poring out of his ears. That the best explanation some teachers can give for suddenly aberrant behavior among Junior High kids. ;) ]
Assuming that the chased guppy is not a female, you might eventually have to return the chasing male or buy a few more males. If your tank hasn't cycled yet, I wouldn't buy more fish yet. Please check out cycling in the Immediate Help stuff here.
LOL! I did a Google search for male guppy and in the second row under Male Guppy is a very female guppy! Google has the bad habit of including every photo in an article on male guppies or whatever the topic is.
Googling pair of guppies gave several hits which were other kinds of fish. In a site called A Guide to the Freshwater Fishes of Singapore they offer a diagram of the modified anal fin of another livebearer, a common Gambusia. Such a copulatory organ is called gonopodium.
http://habitatnews.nus.edu.sg/guidebooks/freshfish/text/224.htm
They also show fancy guppies and carry an image of a wild (feral) pair of guppies. The much larger female very clearly has a very large dark spot call the gravid spot. She is close to dropping a lot of fry! The male is a little twerp in comparison. It is hard to see his gonopodium.
By the way, Singapore is a long swim for common Gambusia from the eastern US. And it is just as long a swim for wild guppies from Trinidad or the northern shore of South America!
These images may be of more use.
http://www.aqualandpetsplus.com/Livebe6.jpg
http://galerie.zierfischverzeichnis.de/albums/userpics/10001/normal_poecilia_copulation.jpg
A very young male:
http://www.guppywest.com/GuppyCultMale1.JPG
If we wish to sort the young guppies into groups of males and females we have to look for the female's gravid spot. Males like that one above are easy to miss.
Fancy guppies have come a long way from their wild brethren. If we just let anybody breed with anybody, they will regress towards the wild type. :(
http://habitatnews.nus.edu.sg/guidebooks/freshfish/text/224.htm
So after looking at the above images, is your larger guppy (that phrase set off alarm bells) a male or a female? If they are all males, we'll consider at least one other possibility.